Tổng hợp và thăm dò hoạt tính xúc tác của vật liệu Fe-MIL-101 cho phản ứng benzyl hóa Friedel-Crafts

  • Nguyễn Duy Khôi
  • Nguyễn Thanh Bình
  • Phan Thị Hoàng Oanh

Tóm tắt

The synthesis of Fe-MIL-101 material with the presence of H2BDC linker and iron (III) chloride achieving remarkable success is a result of solvothermal method. Catalytic activity works on the Friedel-Crafts benzoylation reaction of aromatic compounds and benzoyl chloride. In addition, Fe-MIL-101 is a heterogeneous catalyst which succeeds in not only shortening duration in a significant amount, but also increasing conversion with the assistance of the microwave irradiation compared with the conventional heating. Fe-MIL-101 would be a very potential alternative in place of unfavourable and dated iron (III) chloride homogeneous catalyst, due to its thermal stability, moreover, it can be recovered and reused after aqueous work-up.

điểm /   đánh giá
Phát hành ngày
2018-01-15